Showing posts with label Material. Show all posts
Showing posts with label Material. Show all posts

New Materials May Allow One-Way Light

Normally, a glass window doesn’t care where a ray of light came from. But special kinds of glass or plastic could be a bit pickier.

Nonlinear materials could distinguish between two rays of light coming from opposite directions, say two Italian physicists. Blocking a ray from one direction and allowing in a ray from the other could be useful for making a one-way street for light.

Textbook optics prohibits this kind of directional discrimination. Everyday linear materials are governed by the reciprocity theorem, which says that a beam of light coming from the left will pass through and reflect off a material in the same way as a beam of light coming from the right.
But nonlinear materials, which can change as light passes through them, play by different rules.

“Without nonlinearity this asymmetry would not be possible,” says Giulio Casati, a physicist at the University of Insubria in Como, Italy.

A textbook pendulum, for instance, swings with a steady frequency that can be calculated from equations. But a nonlinear pendulum’s frequency changes over time in a way that can be worked out only with a computer.

Casati mathematically modeled the behavior of light passing through two layers of nonlinear material. The light changes the properties of the materials as it passes through, which in turn changes the behavior of light in complex ways.

Thanks to this back-and-forth dance, the frequency of light that can pass through these materials depends on the direction of the light, he reports in the April 22 Physical Review Letters.
“Other people have used nonlinearity, but they use it in a different way,” says Panayotis Kevrekidis, a mathematical physicist at the University of Massachusetts Amherst who wasn’t involved in the research.
Previous attempts to break down the reversibility of light used photonic crystals. Those materials can only block a portion of the light that has been boosted to twice its original frequency.
Casati’s initial simulations describe a way to transmit about 80 percent of the light traveling in one direction while blocking about 70 percent of the light coming from the opposite direction.
This selectivity could be useful for making wave diodes. Just as a traditional diode allows electrical current to flow only one direction in a piece of electronics, a wave diode could guide the flow of light in quantum or optical computing.

“This simple model may also apply to more general situations, like acoustics or different kinds of waves,” says Stefano Lepri, a physicist at the Italian National Research Council Institute for Complex Systems in Florence and a coauthor of the study. Materials that respond to sound waves nonlinearly could, he suggests, be useful for one-directional soundproofing.

Image: A proposed wave diode would allow light coming from the left to pass through (image on left) but reflect light coming from the other direction (right). (Stefano Lepri/Physical Review Letters)

Bacterial Biofilms Beat Teflon in Repelling Liquids

Slimy mats of bacteria called biofilms may be the most liquid-repellent materials in nature, researchers have discovered.

“There are a few man-made materials that can perform better, and they have to be made in clean rooms. They’re incredibly expensive and brittle,” said materials scientist Alexander Epstein of Harvard University, co-author of the new study. “Making biofilm is as easy as growing bacteria.”
The goo secreted by Bacillus subtilis bacteria not only deflects water like a lotus leaf, but also repels concentrated alcohol, acetone and even vaporized liquid, according to a study published Jan. 18 in Proceedings of the National Academy of Sciences.

Biofilms are communities of bacteria that stick together using a mixture of sugars and proteins called the extracellular matrix, which takes on a wrinkled form under powerful microscopes (see image below). Since the discovery of bacteria in the late 1600s, most research has covered individual cells. It’s only since the 1990s that scientists have begun to understand the pervasiveness and importance of biofilms.

“We’re realizing more and more that almost all bacteria in nature are found as biofilms,” Epstein said. “It offers a lot of advantages for them, including better protection and increased chances they’ll stick to sources of food. It’s crazy stuff.”

While trying to map the internal structure of B. subtilis biofilm using a vaporized radioactive tracer that would show up in x-ray photos, the researchers found it couldn’t get inside. They were frustrated at first, but Epstein said his team soon realized the significance of the stubborn biofilm.
“We started to put different liquids on it. Concentrated alcohols just [beaded up],” Epstein said. For comparison, the researchers also tried a non-stick Teflon surface. “We found the biofilms substantially superior to Teflon,” he said.

To analyze resistance to wetting, Epstein and his team measured the angle between droplets of liquid and the materials’ surfaces (right). At 10 percent alcohol, similar to wine’s concentration, Teflon started getting wet. Biofilms, however, balled up all concentrations of alcohol up to 80 percent (similar to Everclear). Liquids wetted biofilms only after sitting on them for minutes or hours.
Epstein isn’t suggesting we grow biofilms for frying pans or rain jackets, but thinks the research will inspire practical new applications. His team ultimately hopes to resolve biofilm’s molecular structure to develop new materials.
“We don’t fully understand it, but it’s broadly true that you need both protein and sugars for this repelling property,” Epstein wrote in an e-mail to Wired.com. “Sugars absolutely have to be there, but we don’t know why. We’re doing some followup research on that now,” he said.

Images: Courtesy of PNAS/Alexander Epstein et al. 1) A bead of 50 percent ethanol rests on a biolfilm of B. subtilis bacteria sliced from a Petri dish. 2) Wetness of a surface is determined by the contact angle of liquid droplets, and increases sharply when a droplet’s inner contact angle is less than 90 degrees. 3) A scanning electron micrograph of a mutant B. subtilis strain’s extracellular matrix, or ECM.

Scientists Create Material 10x Stronger than Steel, with Malleability

An Australian university constructed graphene paper by milling graphite, and for the first time it was malleable, 10 times stronger than steel, 6 times lighter, and more rigid at the same time.

A UTS (University of Technology, Sydney) research team recently created strong graphene paper from graphite with a tensile strength ten times greater than that of steel. It is also six times lighter, two times harder, and exhibited thirteen times more resistance to bending than steel, and of course, it does not rust.

Graphene is a material consisting of carbon nanotubes which has very unique property combinations which composite materials do not, such as malleability, exceptional thermal and electrical conductivity, high strength, the ability to be rigid as well, very light weight, and the material required to construct it is not rare. Nothing on the planet has ever even come remotely close to these exceptional characteristic combinations.

The lead researcher Ali Reza Ranjbartoreh said: “No one else has used a similar production and heat testing method to find and carry out such exceptional mechanical properties for graphene paper. We are definitely well ahead of other research societies.”

Ali Reza Ranjbartoreh also added: “The exceptional mechanical properties of synthesised GP render it a promising material for commercial and engineering applications. Not only is it lighter, stronger, harder and more flexible than steel it is also a recyclable and sustainable manufacturable product that is eco-friendly and cost effective in its use.”

There are many implications of such a technological advancement. If affordable, it can:

  • Make significantly stronger, very efficient, more environmentally sound, and lighter vehicles, from economy cars, to trains, buses, ships, and passenger jets.
  • Extend the range and performance of electric vehicles due to its light weight, and reduce the required battery capacity due to less weight, because less weight requires less power, and power is provided by the batteries.
  • Make much stronger, lighter, and more efficient wind turbine blade designs possible. Blades could bend instead of break. It would be able to prevent damage to wind turbine blades caused by lightning strikes. Wind turbine blades are normally constructed with composite non-metals which do not conduct electricity well and therefore cannot safely channel lightning into the ground. When lightning strikes a composite wind turbine blade, the temperature of the air inside it can increase 30,000 degrees Celsius, causing it to expand rapidly (explode). The blades are equipped with lightning receptors at the tip which channel the current into the ground, and this is helpful, but not always enough. Like lightning rods, wind turbines need to be designed so that they attract lightning to conductive materials such as metals that channel them into the ground. In other words, they divert them into the ground so they don’t reach sensitive components, because electricity follows the path of least resistance.
  • All portable devices such as notebook computers, tablet PCs, cellphones, music players, could be stronger while still being lightweight.
Another key advantage of this material is that it is recyclable.
Australian mines happen to contain a large amount of graphite, meaning that the widespread use of such a material in the future could be very beneficial to Australia. This industry is likely to grow in the foreseeable future as it strides up a long path to becoming mainstream.

Mr Ranjbartoreh said that the results of this project promise significant benefits to the use of this material in the aviation and automotive industries.

Physorg
Images via University of Technology Sydney

Solar Cell Efficiency Could Be Boosted by Minimizing Defects

Nano-cones could help neutralize manufacturing defects in solar cells

A new advance in solar cells that tips the surface with minuscule cone structures could neutralize manufacturing defects, boosting efficiency up to 80 percent.

In conventional solar panels, more than 50 percent of the charges generated by sunlight are lost due to defects, said Jun Xu, a researcher at the Department of Energy's Oak Ridge National Laboratory. The irregularities in the formation of the crystalline structure of solar cells can trap electrons and limit the transfer of sunlight to electrical energy.


 SOLAR FLAWS: Manufacturing defects impair solar cells ability to turn sunlight into electricity, but a new technique might help minimize the flaws. Image: Stephan Kambor via Wikimedia Commons

This is why Xu and his team are looking at how nanocones -- cone-shaped structures one-millionth of a meter long -- can neutralize the burden of defects.

The negative-polarity nanocones are made of zinc oxide, and surrounded by a positive-polarity cadmium telluride semiconductor that absorbs sunlight. The three-dimensional cone structure acts as a junction between the zinc oxide and cadmium telluride, making for a smoother conversion of the solar charge to electricity.

The idea, said Xu, is not to "fix" the defects, but to make them irrelevant. With the nanocone structure, the team was able to increase the overall electric charge to overcome the pitfalls of defects.
"If [manufacturers] make a defect with no way to solve it, we make the defect less relevant," he said. "You need to increase the efficiency ... you need to be able to increase change of transport. With a nanocone structure, you can do that."

On a small level, the efficiency gains are relatively minor -- rising to 3.2 percent, compared to 1.8 percent for panels without the nanocones. But Xu believes this will pay off on a larger scale.
"Our efficiency is moderate in generation, but the difference between the two platforms is huge," he said, referring to the models with and without nanocones. In the real world, even a much smaller percentage increase would be an important achievement for solar.

"If we can reduce the defective material, and we can increase the efficiency about 15 or 10 percent," he said, "that would be a huge success."

Zinc oxide and cadmium telluride serve as relatively cheap materials to create nanocones, as well, said Xu, with the potential to reduce the cost of commercial solar panels if applied to silicon -- the most common material used for solar panels.

The research will be published in the Institute of Electrical and Electronics Engineers' IEEE Proceedings.

From Climatewire with permission from Environment & Energy Publishing, LLC. www.eenews.net, 202-628-6500

The Emergence of Holographic Video

Experimental networked display refreshes holograms every two seconds

An image of an F4 Phantom fighter jet created with the new 3D telepresence system.
Researchers at the University of Arizona (UA), Tucson, have developed a holographic system that can transmit a series of 3D images in near-real-time, a precursor to holographic videoconferencing.

The system incorporates a novel, photorefractive polymer--one that can rapidly refresh holographic images and is scalable for production--coupled to a unique system for recording and transmitting 3D images of individuals and objects via Ethernet.

Lead author Pierre-Alexandre Blanche and his colleagues from the university and Nitto Denko Technical Corp. of Oceanside, Calif., describe the breakthrough in the cover story of the Nov. 4, 2010, issue of Nature.

"This advance brings us a step closer to the ultimate goal of realistic holographic telepresence with high-resolution, full-color, human-size, 3D images that can be sent at video refresh rates from one part of the world to the other," says co-author and project lead Nasser Peyghambarian of UA and the Director of NSF's multi-institution Engineering Research Center for Integrated Access Networks (CIAN).

The researchers had previously demonstrated a refreshable polymer display system, but it could refresh images only once every four minutes. The new system can refresh images every two seconds; while not yet ideal for a display, the rate is more than one hundred times faster.

Additionally, using a single-laser system for writing the images onto the photorefractive polymer, the researchers can display visuals in color. While the current refresh rate for multi-color display is even slower than for monochromatic images, the development suggests a true 3D, multicolor system may be feasible.
"This breakthrough opens new opportunities for optics as a means to transport images in real time," says Lynn Preston, director of the NSF Engineering Research Centers program that supports CIAN. "Such a system can have an important impact on telepresence, telemedicine, engineering design and manufacturing, and other applications. This is an early and tremendously important outcome from this three-year old center."
More information is available in the UA press release.



Project lead Nasser Peyghambarian of the University of Arizona, who is also director of NSF's multi-institution Engineering Research Center for Integrated Access Networks (CIAN), explains the technology--a holographic system that can transmit a series of 3D images in near-real-time, a precursor to holographic videoconferencing.

Credit: National Science Foundation




A hologram of a member of Peyghambarian's lab appears in the photorefractive polymer screen. Moving the camera from side to side reveals what the researchers call parallax, one of the novelties of this research: The holographic image presents itself from different perspectives as the viewer moves his or her head from side to side or up and down.

Credit: N. Peyghambarian, University of Arizona
 



This holographic representation of a vase shows different colors capable with the new system and an effect known as parallax, which makes the image life-like: As the viewer moves his or her head from side to side or up and down, the holographic image presents itself from different perspectives.

Credit: N. Peyghambarian, University of Arizona
 



A pulsed 50-Hz Laser inscribes a holographic image of a F-4 fighter jet into the photo-refractive polymer screen.

Credit: N. Peyghambarian, University of Arizona




A laser inscribes a series of holograms into the photorefractive polymer screen. Each iteration of the writing process takes only two seconds.

Credit: N. Peyghambarian, University of Arizona



Study co-author and project lead Nasser Peyghambarian of the University of Arizona, Tucson, the director of NSF's multi-institution Engineering Research Center for Integrated Access Networks (CIAN).

Credit: University of Arizona


Team member Vivian Sieh holds up the photorefractive polymer that has enabled the new 3D telepresence system to achieve a two-second refresh rate.

Credit: University of Arizona
 

This material is based upon work supported by the Engineering Research Center Program of the National Science Foundation under NSF Cooperative Support Agreement Award No. EEC-0812072
 
-NSF-
November 3, 2010
Press Release 10-207

Carbon Nanotubes Boost Power of Lithium Battery

A new battery demonstrated a power output 10 times higher, for its size, than what is expected of a conventional rechargeable lithium battery.
Imagine that the same rechargeable battery in your cell phone could power a device that requires 10 times the energy. That possibility may be closer than you think.

A battery created by researchers at Massachusetts Institute of Technology demonstrated an increased capacity for charge by roughly a third and a power output 10 times higher, for its size, than what is expected of a conventional rechargeable lithium battery. The results were published yesterday in Nature Nanotechnology.

The research team, led by Yang Shao-Horn, an associate professor of materials science and mechanical engineering, and Paula Hammond, professor of chemical engineering at MIT, achieved this by creating an entirely new kind of electrode -- in this case, by modifying the positive end of the conventional battery, which is called the cathode.

The collaboration began through graduate student Seung Woo Lee, studying fuel cells, who was advised by both Shao-Horn and Hammond. Lee defended his doctoral dissertation this spring.

Using commercially available carbon nanotubes -- hollow cylinders 50,000 times thinner than a human hair but composed of carbon atoms -- the team fabricated the cathode entirely out of the nanotubes put down in layers.

The large surface area of a nanotube allows it to store more charge than other types of carbon, such as graphite, but previous battery fabrication methods tended to obscure these surfaces.

Using the exposed surfaces allows more charge to be stored -- increasing capacity -- while also letting those charges migrate more easily -- increasing power.

The findings of this research challenge the conventional wisdom about what materials could be used in the cathode of a battery. It also stimulates discussion about what such powerful batteries could be used for.

Small scale experiments so far

Increased power output makes for a great capacitor as well, by efficiently storing charge and delivering that energy precisely when it is needed. Their work, Shao-Horn said, could "lead to a device with performance that bridges batteries and electrochemical capacitors."

So far, the thickest cathode the group has made for these experiments is only 3 micrometers -- 3 one-thousandths of a millimeter. This is tiny when compared to conventional lithium-ion batteries that have electrodes roughly 100 to 200 micrometers thick.

In their present form, Shao-Horn said, their cathode "could be ideal for microelectronic devices."
But these battery-capacitors are also useful in a number of other applications such as emergency power, "energy capture and power assist in cars, trucks and machinery requiring many start-stop cycles," said Shao-Horn. Successfully scaling up this design could dramatically reduce the inefficiencies in future lithium-ion batteries.

However, Shao-Horn preferred to err on the side of caution when peering into the future of this new technology, saying they are only just beginning to understand the underlying chemistry involved.
"Further work is required," said Shao-Horn, "to demonstrate that power and energy performance is maintained with thicker electrodes." A crucial next step of this research is to demonstrate an electrode with a thickness of 50 micrometers -- more than 10 times the size of what they made for their experiments.

The next phase is scaling it up

Doing so would allow the researchers to test whether the electrical properties of the carbon nanotubes can be successfully scaled up to greater and greater thicknesses. Potentially, Shao-Horn said, there is "no limit" on thickness. But in order to do this, Hammond's expertise in biomaterials will be essential.

The layer-by-layer fabrication technique used to make the 3-micrometer-thick carbon nanotube electrode described in the published paper was an extremely time-consuming process. For each layer of nanotubes, a sample had to be dipped into a solution awash with nanotubes.

Then, covered in the solution, the sample had to be left out for 15 to 20 minutes as gravity slowly pulled the nanotubes down through the liquid and onto the sample surface. This procedure had to be repeated about 400 times in order to pile up enough layers to reach a thickness of 3 micrometers.

To bring the layering process up to reasonable, commercially viable speeds, Hammond is appropriating an automatic spray technique she developed for producing layers of polymer materials.

"The spray method is 40 to 100 times faster," she said, taking only seconds to lay down each new layer of nanotubes rather than the 15 to 20 minutes it normally takes. The true test will come once much thicker electrodes are tested.
Other battery research from Shao-Horn's group has been highlighted in other ClimateWire stories.
Reprinted from Climatewire with permission from Environment & Energy Publishing, LLC. www.eenews.net, 202-628-6500
 | June 22, 2010

NanoCamo Is the Next Small Thing in Fashion

A new nanoassembly technique could make chameleon-like camouflage possible.

By using specially-designed proteins as nanomotors, Sandia National Laboratory researchers have created a system that can assemble quantum dots into bright, fluorescent rings. In this video, you can watch the formation of those rings, which are about five microns across, less than a tenth of the width of a human hair.
If these quantum dots were embedded on the surface of an object, the formation of the rings would cause the object to change color to the naked eye. Reverse the process and the color would change back. That raises the possibility of fast color changes of the sort that some animals use to blend in with their environments.
“Camouflage outfits that blend with a variety of environments without need of an outside power source — say, blue when at sea and then brown in a desert environment — is where this work could eventually lead,” George Bachand, the principal investigator at Sandia said in a press release.
But that’s probably a decade or more away, Bachand said.

Nobel Worthy: Best Graphene Close-Ups

Sorry diamond lovers, but graphene is the most awesome form of carbon out there. Evidence: Andre Geim and Konstantin Novoselov, the two scientists who isolated one-atom-thick sheets of the stuff in 2004, won the Nobel Prize this morning -- netting themselves a pot of 10 million Swedish kroner (about $1.49 million).
Despite its razor-thin makeup, graphene is one of the strongest, lightest and most conductive materials known to humankind. It’s also 97.3 percent transparent, but looks really cool under powerful microscopes. We’ve corralled some of the best shots here, with a bonus video of graphene being punished by an electron beam.

Mmmm... Graphene Cake

Theoretical physicist Philip Russell Wallace predicted graphene’s existence in 1947, but it wasn’t until the 1960s that scientists began looking for it in earnest. Forty years later, researchers practically wrote off isolating single-layer graphene. If the hexagonal layers didn’t roll up into buckeyballs or nanotubes, so the thinking went, they’d disintegrate entirely.
Geim and Novoselov persisted, however, and figured out how to isolate it using objects common to any office: Scotch tape and graphite, which is found in pencil leads.
At the top-right of this image is a 10-micron-wide, 30-layer-thick slice of graphene sheets.

Image: Science

Between the Graphene Sheets

The problem with seeing a single sheet of graphene is that it’s practically invisible.
To prove in 2004 that they’d isolated one using the tape-and-graphite method, Keim and Novoselov peeled off a single flake of graphene and stuck it onto silicon dioxide (the same stuff used to make semiconductors in electronics). Similar to how a sheen of oil becomes visible in a rainbow of colors on water, the combination of graphene on oxidized silicon revealed the flake in an electron microscope.

Image: Science

There's a Hole in My Graphene

Graphene may be the strongest carbon-based material, period, but it can’t stop a beam of electrons.
In this video, Berkeley Lab scientists subject an unsuspecting sheet of graphene to the punishment of a powerful electron beam. The beam punched a hole in the graphene, causing individual carbon atoms to scramble for a spot to stick at the hole's edge.

Video/image: Lawrence Berkeley National Laboratory


Pounding the Graphene Skins

Graphene drum? Check. Laser microphone? Check. Rock on.

In a 2007 test of graphene’s ability to resonate, researchers at Pomona College in California and Cornell University in New York stretched a 2-nanometer-wide ribbon of graphene over a silicon dioxide trench, then used an electrode to vibrate the sheet.

Image: Science

Graphene Bubble

Graphene is made up of carbon arranged into chicken-wire-like hexagonal rings, yet the bonds between any carbon atoms can stretch up to 20 percent. The arrangement may seem innocuous, yet it paves the way for quantum mechanical weirdness to manifest itself.

Case in point: When scientists sandwiched graphene onto platinum, then popped out a microscopic bubble, electrons in the graphene sheet behaved as if they were being punished by a magnetic field stronger than any ever produced in a laboratory. No magnetic field was in sight, so the effect was called (naturally) pseudo-magnetism.

Image: Lawrence Berkeley National Laboratory

Ribbons 'O Graphene

To say graphene conducts electricity well is a gross understatement. The electrons buzzing around graphene’s carbon atoms are unusually free to roam and behave more like massless pieces of light called photons. This allows graphene to be used like a high-performance transistor capable of operating at speeds 100 to 1,000 times faster than silicon-based transistors.

Trouble is, graphene moves electrons around a little too well. The threshold between graphene’s on/off state is exceedingly small, causing it to conduct electricity even in an “off” state. By growing micron-thin ribbons of graphene (above) instead of full sheets, however, chemists like Hongjie Dai at Stanford University have raised that threshold more than 10,000 times. Further improvements could lead to high-speed graphene-powered electronics.

Image: Hongjie Dai/Stanford University

Graphene Transistor

Capitalizing on graphene’s electrical awesomeness, HRL Laboratories (owned by Boeing and General Motors) built the world’s first functional radio frequency (RF) transistor using graphene in 2008. The tiny device, known as an RF field-effect transistor, can pick up radio frequencies while hardly gobbling any electrical power.

The company has since scaled up a full-size chip of the transistors, but alleged practical uses in imaging and communications remain to be seen.

Image: HRL Laboratories
By Dave Mosher Email Author October 5, 2010

New X-ray Camera Sees Through Melting Metal

A new high-speed X-ray video camera, now the fastest in the world, can see through molten metal and watch weld-weakening flaws form in real-time.
 
The $670,000 device successfully captured X-ray footage on Nov. 23 at 5,000 frames-per-second (fps), or five times faster than previous X-ray cameras (and 83 times faster than a consumer camcorder). The high-speed video above shows a laser welding solid aluminum in visible light, followed by the new X-ray-light welding clips.

“With visible light, we could only see the surface of the welding process. You couldn’t see what was happening inside,” said Felix Abt, one of the camera’s designers at the University of Stuttgart. “The only way to see pores that weaken weld seams was to cut the metal into pieces.”


Automotive companies use robots equipped with high-powered lasers to seam cars together with extreme speed and precision. As laser welding continues to get “more powerful, move faster, go deeper” and increase in use, Abt says, it’s increasingly important to understand the dynamics involved.

“Laser welding creates very high-pressure, high-velocity, fluctuating environments. You’re boiling metal that’s cooling almost instantly,” Abt said. “This leads to instabilities that weaken your weld.”

To capture the welding process in action, Abt and his colleague Rudolph Weber use an industrial-strength 4-kilowatt laser, which is roughly 400,000 times more powerful than a DVD drive’s beam. As their laser pummels a hunk of metal moving on a track, a tube fires X-rays through the weld and toward a high-speed video camera.

As a frame of reference, the first clip shows 10,000 fps visible light footage zoomed in on a small 10-by-5-millimeter frame. The fuzzy 1,000 fps and 5,000 fps clips that follow are the new ones filmed in X-ray light.
“The white structure on left is where the laser hits. That’s a capillary of metallic steam,” Abt said, noting aluminum boils at 4,400 degrees Fahrenheit. Whitish globules that break off the capillary are weld-weakening pores that cool in a matter of microseconds.

The new X-ray footage isn’t pretty, Abt says, but in a few months he and Weber will tune the camera to increase its clarity. They also plan to imbue welding samples with tracer materials, such as tungsten carbide, that absorb X-rays and improve image contrast.
“This is really only the beginning, but we now have the ability to watch processes that lead to porosity in real time while we’re welding,” Abt said.

Video: A 4-kilowatt laser melts solid aluminum. The first clip is 10,000 fps in visible light, followed by 1,000 fps and 5,000 fps in X-ray light. Credit: Felix Abt, Rudolph Weber/University of Stuttgart
Image: The device Abt and Weber constructed to record laser welding in X-ray light. The laser hangs from the ceiling, the X-ray cathode is on the left (as the welding itself doesn’t produce X-rays) and the digital video camera is on the right. An exhaust vent pulls fumes away from the rig during welding and a track below moves a metal sample during recording. Credit: Felix Abt/University of Stuttgart

As China Advances, Solar Start-Ups Strategize

Over the last two years, Chinese solar panel makers like Suntech and Yingli Green Energy have moved aggressively into the United States and now supply about 40 percent of the California market, according to Bloomberg New Energy Finance, a research firm. 

China’s growing dominance of the global solar market has been on display in Los Angeles this week at the Solar Power International conference, one of the industry’s biggest annual get-togethers. In a vast exhibition hall, the booth of one Silicon Valley start-up, Solyndra, is surrounded by a sea of Chinese solar companies offering their wares. 

As prices for conventional silicon-based solar panels plummet, pressure has increased on Silicon Valley start-ups like Solyndra that make a type of photovoltaic cell called copper indium gallium selenide, or CIGS. Though less efficient at converting sunlight into electricity, the promise of the technology was that it could be made cheaply – at least until the cost of conventional solar module prices fell 40 percent over the past year.
That led Solyndra to start production two months ahead of schedule at its new $733 million factory in Fremont, Calif., and to speed up development of its next-generation solar panel. 

“It definitely puts more pressure on us to bring our costs down as quickly as possible by ramping up volume,” said Ben Bierman, Solyndra’s executive vice president for operations and engineering, as driverless carts shuttled stacks of photovoltaic parts to large orange robots at Fab 1, the company’s original factory.
Nathaniel Bullard, a solar analyst with Bloomberg New Energy Finance in San Francisco, said that success for high-tech Silicon Valley solar companies may depend on finding a big market niche they can dominate.
Solyndra, for instance, makes lightweight solar panels that snap together like Legos and can be installed on large commercial rooftops unable to support heavier conventional panels. On the roof of the company’s headquarters, Mr. Bierman recently gave me an advance look at its new solar panel, which is more powerful but requires far less labor to install. 

Production started two months early at Solyndra’s solar panel factory in Fremont, Calif.

“We really took a lot of the cost out and accelerated development in response to the Chinese,” Mr. Bierman said. 

China presents different challenges for SunPower, which was founded in 1985 and is the granddaddy of Silicon Valley solar companies. 

SunPower makes conventional solar panels but has also pursued a high-technology strategy and says it produces the world’s most efficient photovoltaic modules. (Architects and fashion-forward homeowners also favor the company’s sleek jet-black panels.)

In recent years, SunPower has increasingly focused on building big photovoltaic power plants to supply electricity to utilities that put a premium on technological performance, reliability and a company’s ability to manage complex projects.

“In the old days, the saying was that nobody gets firedfor buying I.B.M.,” Thomas Werner, SunPower’s chief executive, said in an interview. “That’s what we want to be in solar, and we are in fact.”
He said that while SunPower competes on costs, it does not aim to be the lowest-cost manufacturer.
“We want to have the best technologies so that people buy us for the reasons they buy a company’s product like Apple,” Mr. Werner said. “I don’t want to be the iPhone without the apps.”

Çin'in Güneşi Amerika'yı Yakıyor

 FREMONT, California - Silikon Vadisi girişimleri bir zamanlar güneş panelleri yapmak için kullanılan teknolojiyi yenileyip üretim maliyetlerini büyük ölçüde keserek güneş enerjisi sektörünü tepeden tırnağa değiştirmeyi hayal ediyordu. Yüksek teknoloji uzmanları tarafından kurulan şirketler sonunda seri üretime başlıyor ancak sektörün zaten değişmiş olduğunu fark ediyorlar. 

 Kendi hükümetleri tarafından sübvanse edilen Çinli şirketler, seri üretime geçip güneş panellerinin fiyatı düşürdü ve herkesi hayret ettirecek bir hızda pazarı ele geçirdi. Araştırma şirketi Bloomberg New Energy Finance'a göre, Çinli güneş paneli üreticileri ABD'nin en büyüğü olan California pazarının yaklaşık yüzde 40'ını ve Avrupa pazarlarının büyük bir kısmını ele geçirmiş durumda.

 Şanghay'daki JA Solar'ın CEO'su Fang Peng, "Her geçen yıl büyüyoruz. Bu yıl sonunda 1,8 gigawattlık kapasitemiz olacak. Ayrıca yıl başında 4 bin olan çalışan sayımız yıl sonunda 11 bine çıkacak" diyor. Kıyaslamak gerekirse, Silikon Vadisi'nde bulunan Solyndra şirketi 2011 sonunda 300 megawattlık üretim kapasitesine ulaşmayı umut ediyor. MiaSolé'nin Başkanı Joseph Laia, "Güneş enerjisi piyasası o kadar değişti ki, ağlayacak gibi oluyorum. Maliyet konusuna beklediğimizden 1 veya 2 yıl önce odaklanmak zorunda kaldık" diyor. Geniş kamu ve özel sektör desteğine rağmen Solyndra büyük zorluklarla karşı karşıya. Sektörün en büyüklerinden olan şirket, yatırımcılardan 1 milyar dolardan fazla topladı. Federal hükümet, şirketin yeni güneş paneli fabrikası için 535 milyon dolarlık kredi temin etti. Ancak Solyndra'nın fabrikası inşa edilirken, ithal edilen Çin malları yüzünden güneş modüllerinin fiyatı yüzde 40 düştü. Bunun üzerine Solyndra planlanandan iki ay önce, 13 Eylül'de panelleri piyasaya sürdü. Ayrıca daha pahalı olan panellerinin kurulum maliyeti hesaba katılınca aslında Çin mallarına göre daha uygun olduğuna müşterileri ikna etmek için bir pazarlama kampanyası başlattı. Solyndra'nın operasyonlardan ve mühendislikten sorumlu başkan yardımcısı Ben Bierman, "Pazarın durumu maliyetleri düşürmemiz için bizim üzerimizde bir baskı unsuru oluşturuyor" diyor. Bir zamanlar Silikon Vadisi'nin yeni isminin "Güneş Vadisi" olacağını öngören yatırımcılar, artık şirketlere para aktarmak konusunda daha tedbirli davranıyor. 

 San Francisco merkezli araştırma şirketi Cleantech Group'a göre, 2010'un üçüncü çeyreğinde, güneş paneli şirketlerine yapılan girişim sermayesi yatırımı 144 milyon dolara indi. Bir önceki yıl aynı dönemde bu rakam 451 milyon dolardı. Solyndra ve MiaSolé gibi bakır indiyum galyum selenyum (CIGS) kullanarak fotovoltaik hücreler üreten şirketler, bilhassa zarar gördü. Silikon plakalardan yapılan geleneksel güneş panellerinin aksine, CIGS hücreleri, cam veya esnek malzemeler üzerine yerleştirilebiliyor.

"İnce filmli" güneş panellerinin avantajı, ucuza mal edilmeleri olmalıydı ancak CIGS hücrelerinin seri üretimi beklenenden daha zor oldu. Silikon Vadisi'ndeki şirketler sorunu çözmeye çalışırken, silikon fiyatları düştü ve hükümetlerinden destek alan Çinli şirketler geleneksel güneş panellerinin üretimini hızla artırdı. Eylül ayında Sharp tarafından satın alınan güneş paneli üreticisi Recurrent Energy'nin Başkanı Arno Harris, Çin hükümeti tarafından sübvanse edilen Yingli Green Energy ile tedarik anlaşması imzalandıklarını açıkladı. Çinli şirketin ucuz ve kaliteli ürün ve finansman sunduğunu söylüyor. Harris, "Bu anlaşma sayesinde verimli şekilde finanse edilmiş projeler üzerinden rekabet edebilir teklifler verebileceğimizi fark ettik" diyor. 

 Çin'den gelen rekabet yüzünden Silikon Vadisi şirketleri alternatif stratejiler üretmek zorunda kaldı. Girişim şirketi Innovalight, "silikon mürekkep" adı verdiği ve sürülünce silikondan yapılan standart güneş hücresinin verimliliğini arttıran bir ürün geliştirdi. Innovalight yöneticileri, Çinlilerle rekabet etmek için kendi fabrikalarını kurup yüz milyonlarca dolar harcamak ve yerine ürünü Çinlilere lisanslamaya karar verdi. Innovalight'ın Başkanı Conrad Burke, "Sübvansiyon, düşük faizli krediler, ucuz işgücü ve sizi güneş enerjisinde 1 numara yapmaya çalışan bir devlet stratejisiyle nasıl baş edebilirsiniz ki?" diye soruyor. 

"Amerikan stratejisinin merkezinde inovasyon olacak. Bu Çin'deki ölçüde bir üretim sağlamayacak ancak Çin'e en son teknolojiyi satıyoruz ve burada iş olanakları yaratıyoruz" diye ekliyor. Yine de bir diğer Silikon Vadisi şirketi SolarCity'nin Başkanı Lyndon Rive, şirketinin perakende devi Wal-Mart için, çok sayıda geleneksel güneş paneli kuracağını söylüyor. Ancak bu panellerin neredeyse hepsi Çin'de üretilmiş olacak.

 By TODD WOODY

How Modified Worms and Goats Can Mass-Produce Nature's Toughest Fiber

After years of research, we may be close to full-scale production of super-strong spider silk 
Mutant silkworms can produce miles of super-strong silk, in a new breakthrough that could lead to mass production of tough, flexible spider-silk material. Thanks to the efforts of these genetically modified spider-worms, along with spidergoats and spider-alfalfa, spider clothes may soon be upon us.
Randy Lewis, a molecular biologist at the University of Wyoming, has been milking his spidergoats for a couple years now, and he’s been trying to improve yields of genetically engineered spider-silk alfalfa. He’s researching improved synthetic spider silk genes, and he hopes to start growing spider cotton in the near future. With his latest research, spider fabrics might only be a year away.

Last week, Lewis and Malcolm Fraser at the University of Notre Dame announced they bred silkworms that had been genetically engineered to produce spider silk.

“From our perspective, there are huge advantages to the fact that the fiber is already spun,” Lewis said. “You don’t have to purify the protein, you don’t have to take it and spin fibers.”
Lewis said the study, which has not yet been published, proves the concept of engineering and breeding transgenic silkworms.

Silkworm: A mature silkworm is pictured just before it starts spinning its transgenic silk.  University of Notre Dame

“The real question is going to be, can we make the necessary improvements in the mechanical properties of the silkworm silk by incorporating the spider silk in it? If we can do that, then obviously it makes a whole lot of things possible in terms of the amount of material you can make.”
A single silkworm cocoon contains more than a half-mile of silk thread, so colonies of transgenic silkworms produce plenty of silk, said Fraser, a molecular biologist at Notre Dame. He believes industrial production of engineered spider silk could happen within a year.

Spider silk is one of the most valuable materials in nature. It could be used for a vast array of products, from artificial ligaments to super-strong wound dressings or even body armor. Lewis envisions spider-silk replacement tendons, parachute cords and more.

Silk could even be used to transport drugs or act as nanoscale transistor scaffolds. In a study last year, scientists at Legacy Clinical Research & Technology Center in Portland, Ore., demonstrated that silk-based brain implants containing adenosine can suppress seizures in rats. In a paper published in the journal Science in July, Tufts University researchers said silk could be used to build flexible and degradable displays or even implantable optical systems for medicine.

“There’s lots of things you can do with fibers that you can’t do with something that comes as an amorphous blob or a solid,” Lewis said.
Nano-fabrics could be even stronger than spider silk, but as of now they’re impossibly small. Last week, Canadian researchers reported building the longest-ever polyyne chain — polyyne carbon-carbon bonds are even stronger than those in graphene — but it was only 44 carbon atoms long.

Nano-sized fibers are still limited. “We can make textile quantities of the silkworm silks,” Fraser said. “Nanotechnology is certainly something that has some awesome potential, but I don’t know how soon that potential will be realized, and even if it is realized, I’m not sure that it would replace many of the medical applications of natural silk fibers, which are considerable.”

Lewis has been working on those applications for two decades. It’s been 12 years since he first isolated the genes that produce high-performance spider silk, and he garnered international attention for his transgenic goats, whose DNA has been altered to produce the proteins necessary to make spider silk. When the goats give birth and start lactating, they produce spider silk proteins in their milk, which is collected, purified and spun into silk, Lewis said.

It would be easier to milk spiders than mutant goats, if only spiders were not so murderous and territorial. As it is, spider farms have not proven a successful venture, whereas there are long traditions of farming both silkworms and goats. Scale makes a difference too: Lewis can get half an ounce of silk from every quart of milk. It would take 100 spiders to obtain that amount.

Transgenic silkworms could be even more productive. Breeding them involved some sneaky DNA, however. Kraig Biocraft Laboratories Inc., a Lansing, Mich., firm, partnered with Fraser, who discovered and patented a DNA transposon called “piggyBAC.” The transposon can insert itself into a cell’s genetic material. The researchers used piggyBAC to incorporate snippets of spider DNA into silkworm embryos, resulting in silkworms that spin a hybridized part-silkworm, part-spider silk.

The researchers wanted to be sure they could breed the spiderized silkworms, so they also added fluorescent protein to the spider DNA. The mutant silkworms had glowing red eyes, and their silk was fluorescent green.
Fraser said he is completing molecular analyses before submitting his study to a research journal. Meanwhile, he hopes to continue improving the snippets of spider DNA — especially if scientists obtain a sequence for a brand-new spider just discovered in Madagascar. The Darwin’s bark spider makes the largest webs in the world, spinning silk that is 10 times stronger than Kevlar.

Fraser also studies HIV and hepatitis, and he hinted that piggyBAC-hacked silkworms might be useful for other applications: “Silk isn’t the only protein that silkworms can produce,” he said.
Lewis said his highest priority is figuring out the fastest and most efficient way to produce large quantities of silk. He also hopes to continue isolating new spider silk genes and incorporating them into his formula. As of now, his formula is a blend of several different spider proteins, mainly from the golden orb weaver.
Lewis also hopes to start breeding cotton plants that contain the protein necessary to make spider silk. Cotton seeds already contain protein, and they’re considered a waste product, Lewis said.

“If we can take and use something that nobody is going to eat and that doesn’t have much value, and use that as a production system, then we have very little impact on food and fiber, and we can use the methods that are already out there,” he said.

Then spider clothes might not be far off at all.

In New Attempt to Build a Practical Military Laser Weapon, Lockheed Inverts a Prism

Lasers can be powerful weapons — they can take down an aircraft at long ranges and in unstable conditions, for instance. But they are hampered by power and size limits, so they’re not widely used by the military (yet).
Lockheed Martin has a solution: a fiber laser that basically works like a backward prism.


Laser-Powered Warfare Lockheed's RELI laser, developed under a DARPA contract, works like an inverse prism to focus several different wavelengths of laser light. Lockheed Martin
 
Lockheed is among three firms recently awarded contracts to develop a laser for the military’s Robust Electric Laser Initiative, which seeks to improve the power of electric lasers. Fiber lasers are efficient and compact, but until now they have been weaker than other types, like chemical lasers. The RELI program seeks to improve laser strength while reducing power and cooling, so systems can be small enough to install on ships or airplanes.

A Lockheed subsidiary developed a first-of-its-kind high-powered fiber laser capable of producing 100 kilowatts or more, according to Lockheed. It uses fiber optics to produce near-perfect beams. The method also confines the laser light to the fiber’s glass structure without using mirrors or other optics.
John Wojnar, director of business development for the laser systems business, said in a September issue of Aviation Week that it works like a inverse prism: lasers with slightly different wavelengths enter a combiner, and the result is a single, focused beam. It’s called Spectral Beam Combining.
Lockheed won an initial $14 million contract from the US Army Space and Missile Defense Command to develop the system. Along with General Atomics and Raytheon, the firm must demonstrate a 25 kW system that can be scaled up to 100 kW within five years.
General Atomics will improve its Hellads distributed-gain laser approach to improve efficiency, while Raytheon will pursue a planar waveguide laser, according to Aviation Week.
Northrop Grumman is also expected to obtain a RELI contract.

Piezoelectric Nanowires Turn Fabric Into Power Source

Wouldn’t it be great if you could rock Kanye West’s outfit from the Grammys, but without the bulky battery pack? Power gadgets by plugging them into your collar? Or do as-yet-undreamed things with garments that produce their own electricity?

It could happen. In a paper published today in Nature, scientists from the Georgia Institute of Technology grew zinc oxide nanowires around kevlar textile fibers. Then the researchers wove the fibers together; when the wires rubbed against each other, an electric charge built up and was channeled into a cathode output.

The fabric is the latest and most personalized form of piezoelectric power generation, in which mechanical stress is turned into electricity. Other piezoelectric garments have been proposed, but they involve polymer inserts rather than fundamentally charge-generating textiles.


The Georgia researchers say their fabric (modeled at right) could have military uses purposes in places where other types of power generation are impractical. That’s no doubt true, and invoking the military is a great way to get funding — but the civilian possibilities are endless! Just put Trevor Baylis on the case.
Microfibre–nanowire hybrid structure for energy
scavenging
[Nature]


Video: Smart Metal Remembers its Shape Like the Terminator

To anyone unfamiliar with materials science, nitinol objects may seem magical.
Squish them, twist them, or bend them — it doesn’t matter. Just add heat and the nickel-titanium blend will return to its original shape.
Apply a strong enough electrical current to a bent nitinol wire and the resulting warmth will cause it to flex like muscle.
Artists have used the curious alloy to make garments with moving parts and breathe life into felt gills and scales.
Engineers have tested it as an artificial muscle for animating robots

Make Like a Leaf: Next-Gen Paint Could Strike Lotus Pose

Lotus leaves stay dry by using the natural vibrations of their environments to shake off water, and manmade materials should be able to mimic the water-repelling technique.

New research published today in Physical Review Letters by Duke materials scientist Chuan-Hua Chen has solved a long-standing puzzle: how lotus leaves stay dry in the wild, but not in the lab.

Chen, who grew up surrounded by lotus plants in his hometown of Honghu in central China, had an intuition that perhaps the leaves used the vibrations induced by the wind to stay dry, but that had never been shown in the lab.

So, Chen and his graduate student, Jonathan Boreyko, stuck lotus leaves, on which they’d condensed water, atop the woofer of a $20 Radio Shack speaker to vibrate the leaf at about 100 hertz — and recorded what happened with a very high-speed camera. Just as in their natural state, the leaves stayed dry.

“People have observed that condensation forms every night on the lotus leaf. When they come back in the morning the water is gone and the leaf is dry,” Chen said in a press release. “The speaker reproduced in the lab what happens every day in nature, which is full of subtle vibrations, especially for the lotus, which has large leaves atop long and slender stems.”


Lotus leaves are the canonical example of a hydrophobic, or water-hating, material. When drops of water fall on the plants, they roll off. They cannot be wet. At the microscopic level, the surfaces are actually quite rough: Tiny fiber-covered pillars hold up the water droplets, creating a cushion of air that prevents them from sticking to the leaves. If water gets into that air cavity though, the property of the material reverses and starts to love water.

Dew, which forms inside the air cavities presented a major problem for researchers looking for hydrophobic coatings for vehicles, say. They worried their materials would be ruined by actual field usage.
“Much remains to be done to achieve genuine antidew materials,” summarized French materials scientist David Quere, in a 2008 article in the Annual Review of Materials Research (.pdf).

The real problem, though, was that the leaves had not been allowed to move as they would in natural conditions. Now, with the discovery that simple vibration can force every drop of water off the leaf, a roadblock has been cleared for hydrophobic materials.


“This finding has direct applications because vibration is everywhere,” Chen told Wired.com. “Your computer has fans, it keeps vibrating. Your power plants, your automobile or your spacecraft all have vibrations.”
Materials, then, can be built to scavenge the tiny amounts of energy in their environments to dry themselves off.

You can watch the process at work in the video below. At first, the water molecules are subtly impaled on the tiny spikes of the lotus leaf. As the vibration commences about halfway through the video, the water droplets at first struggle to break free — and then actually do so. In the language of materials science, the leaf’s surface has gone from a Wenzel state, where it’s not hydrophobic, to a Cassie state, where it is. And that’s the very first time that’s ever been observed in the lab.

Alexis Madrigal
Image: flickr/tapperboy
Source: Wired Mag.

Making Nanomaterials Better, Faster And More Accessible

Stephen Steiner wants to make nanotechnology more accessible to speed up the innovation process.

The inclination to think big goes back to Steiner’s teenage years when he vowed to never drive a car as motivation to solve the world’s energy problem. Now 26, he is a graduate student at MIT working to bring the world next-generation nanomaterials, like nanotubes that can make airplane wires lighter than copper, carbon aerogels that use electrolysis to pull hydrogen from water, and as announced yesterday, nanoparticles that can make super high density batteries.

Steiner’s first task at the MIT lab was to get the nanotube furnaces working manually, but he knew that to really get his lab breakthrough-ready, the furnaces needed to be automated. So he wrote a software program that automates a nanotube furnace using natural English syntax and fuzzy logic to help get us there faster.
"Just give it the instructions you would give an undergraduate and it can execute it," claimed Steiner, "Like ‘when the temperature gets to about 1000 degrees do X.’" This frees up his lab mates from having to spend hours next to the furnace making little tweaks and adjustments every few minutes and allows them to come back later to a batch of freshly baked nanotubes.

The intuitive, small footprint, English-syntax automation program will help the lab figure out how to make longer and more uniform nanotubes faster. Instead of having to babysit a high-maintenance process for hours, the researchers can actually leave the room and focus on other tasks, like analyzing data, or reading the latest literature.

Steiner calls the new program "Ansari" after private space explorer and X Prize sponsor Anousheh Ansari. Her work to open up space flight for all inspired Steiner to try to do the same for nanotech. He is working on a website that he calls "open source nanotech," where people will be able to download his automation software and learn about DIY nanotech.


The aerospace industry has already noticed the promise of nanomaterials and is sponsoring the MIT Nano-Engineered Composite aerospace STructures (NECST) lab. The lab is working to add carbon nanotubes to traditional carbon fiber composites to make them over a million times more conductive, which will save fuel by reducing an airplane’s weight. Seeing the 787 Dreamliner fly this winter with a carbon composite fuselage will be exciting. But seeing a plane that is made entirely of carbon fiber and nanotube-impregnated carbon fiber would be phenomenal.

Loretta Hidalgo Whitesides

Plastic That Heals Itself


Researchers have developed a new material that can fill in its own surface cracks.

Researchers at the University of Illinois at Urbana-Champaign (UIUC) have made a polymer material that can heal itself repeatedly when it cracks. It's a significant advance toward self-healing medical implants and self-repairing materials for use in airplanes and spacecraft. It could also be used for cooling microprocessors and electronic circuits, and it could pave the way toward plastic coatings that regenerate themselves. 
Modeled on human skin, a new material that heals itself multiple times is made of two layers. The polymer coating on top contains tiny catalyst pieces scattered throughout. The substrate contains a network of microchannels carrying a liquid healing agent. When the coating cracks, the cracks spread downward and reach the underlying channels, which ooze out healing agent. The agent mixes with the catalyst and forms a polymer, filling in the cracks.  Credit: J. Hanlon, Univ. of Illinois Beckman Institute 

The first self-healing material was reported by the UIUC researchers six years ago, and other research groups have created different versions of such materials since then, including polymers that mend themselves repeatedly when subject to heat or pressure. But this is the first time anyone has made a material that can repair itself multiple times without any external intervention, says Nancy Sottos, materials-science and engineering professor at UIUC and one of the researchers who led the work.
"It's essentially like giving life to a plastic," says Chris Bielawski, a chemistry professor at the University of Texas at Austin. The ultimate goal would be to create materials that mend themselves, he says, and "this is an amazing proof of concept."

Sottos and her colleagues have designed the new material, reported in this week's Nature Materials, to mimic human skin. If the skin's outer protective layer is cut, the inner layer, which is infused with a dense network of tiny blood vessels, rushes nutrients to the cut to help with healing. The self-healing material consists of an epoxy polymer layer deposited on a substrate that contains a three-dimensional network of microchannels. The epoxy coating contains tiny catalyst particles, while the channels in the substrate are filled with a liquid healing agent.

To test the material, the researchers bend it and crack the polymer coating. The crack spreads down through the coating and reaches the underlying microchannel. This prompts the healing agent to "whip through the channels and into the crack," Sottos says. There, it comes into contact with the catalyst and, in about 10 hours, becomes a polymer and fills in the crack. The system does not need any external pressure to push the healing agent into the crack. Instead, the liquid moves through the narrow channels just as water moves up a straw.

The researchers are able to crack and reheal the surface as many as seven times before the catalyst wears out and stops working. The next generation of the self-healing material should be able to heal itself many more times, according to the researchers. Sottos and her colleagues are designing it so that it will have a two-part system that injects both a healing agent and a catalyst into the crack.
The researchers could also increase the rehealing capacity of the material by hooking up the microchannel network to a little reservoir, Sottos says. If the material runs out of healing agent or catalyst, the reservoir could pump in more.

The material's microchannel design could be a solution to the increasing problem of heat buildup in microelectronics chips. Typically, microelectronic circuit chips sit on substrates that are designed to conduct heat away from the circuit. These heat regulators have their limits. Instead, Sottos says, "you could put a cooling fluid through a [microchannel] network like a little mini-heat exchanger."

Sottos says that researchers could use the same design with other resin and catalyst combinations that can form different polymers. This opens the door for many other applications. While practical self-healing materials might be years away, it's easy to imagine their applications in prosthetics and medical implants made from biocompatible self-healing materials. The cost of the materials might keep them limited, at least initially, to certain high-value, high-performance applications such as use in air- and spacecraft, says Ian Bond, aerospace engineering professor at the University of Bristol, in the United Kingdom.

In the future, different chemistries could lead to cheaper self-healing materials, according to Bielawski. "You could use cheap epoxies ... that you can buy at Home Depot ... as a healing agent," he says.

Prachi Patel - technologyreview.com

Polyurethane Coating Could Make Self-Healing Car Paint

A few years down the road, you may be able to get that scratch out of your car’s bumper simply by parking in a sunny spot. Researchers have created a polyurethane coating that heals itself when exposed to ultraviolet light.

"This new material will have a lot of practical applications," said study co-author Marek Urban, a chemist at the University of Southern Mississippi. “It could coat anything that can be scratched—electronics, aircraft, cars, you name it."

Self-healing coatings could minimize upkeep and repair on a variety of products, saving consumers money and reducing waste.

“Your car would last for a long time, and it would look new for a long time,” Urban said.
The new compound is not the first man-made self-healing material. In 2001, researchers at the University of Illinois embedded tiny liquid-filled capsules in a polymer coating. When the coating cracked, the capsules ruptured, spilling healing agents into the damaged area and repairing it.

One of the Illinois scientists, Scott White, founded a company based on this technology in 2005. Autonomic Materials, Inc. could have self-healing coatings on the market in the next couple of months, according to a recent article in the MIT Technology Review.

Other researchers have devised different methods. In 2002, scientists from UCLA and USC created a compound that heals itself quickly when exposed to high temperatures. The new coating is similar in that it requires an external stimulus to work. But the stimulus—UV radiation—should not be difficult to introduce. A few minutes in the sun would do the trick.

“It’s a new healing chemistry for polyurethane,” said Nancy Sottos, a materials scientist at the University of Illinois who was not involved in the new study.

Urban and co-author Biswajit Ghosh, also of the University of Southern Mississippi, created the compound by mixing chitosan—a derivative of chitin, the main component of arthropod exoskeletons—into polyurethane. They made tiny nicks in the new material, then exposed it to UV light about as intense as that given off by the sun. The radiation set off a series of reactions, causing damaged molecules to link up with each other again. The cuts healed in about 30 minutes.

This repair process, described Thursday in the journal Science, is not moisture-sensitive, meaning it should work in all climates. And making the new coating won’t break the bank, according to Urban.
“It’s very economical,” he said. “You can get chitosan for almost nothing.”
The mending reactions don’t seem to work a second time, so each part of the coating can repair itself only once. But Urban doesn’t see this as much of a drawback in the real world.

“Even if you try to hit the same spot, within a couple of microns, statistically the chances of it happening are very small,” he said.
Citation: "Self-Repairing Oxetane-Substituted Chitosan Polyurethane Networks." By Biswajit Ghosh, Marek W. Urban. Science Vol. 323, 13 March 2009.

Image: Infrared (top) and optical views of a scratch after 0, 15, and 30 minutes of UV exposure. Courtesy of Marek Urban, via Science/AAAS.
Michael Wall

1 Million Spiders Make Golden Silk for Rare Cloth

A rare textile made from the silk of more than a million wild spiders goes on display today at the American Museum of Natural History in New York City.
To produce this unique golden cloth, 70 people spent four years collecting golden orb spiders from telephone poles in Madagascar, while another dozen workers carefully extracted about 80 feet of silk filament from each of the arachnids. The resulting 11-foot by 4-foot textile is the only large piece of cloth made from natural spider silk existing in the world today.

“Spider silk is very elastic, and it has a tensile strength that is incredibly strong compared to steel or Kevlar,” said textile expert Simon Peers, who co-led the project. “There’s scientific research going on all over the world right now trying to replicate the tensile properties of spider silk and apply it to all sorts of areas in medicine and industry, but no one up until now has succeeded in replicating 100 percent of the properties of natural spider silk.”
Peers came up with the idea of weaving spider silk after learning about the French missionary Jacob Paul Camboué, who worked with spiders in Madagascar during the 1880s and 1890s. Camboué built a small, hand-driven machine to extract silk from up to 24 spiders at once, without harming them.

“Simon managed to build a replica of this 24-spider-silking machine that was used at the turn of the century,” said Nicholas Godley, who co-led the project with Peers. As an experiment, the pair collected an initial batch of about 20 spiders. “When we stuck them in the machine and started turning it, lo and behold, this beautiful gold-colored silk started coming out,” Godley said.

But to make a textile of any significant size, the silk experts had to drastically scale up their project. “Fourteen thousand spiders yields about an ounce of silk,” Godley said, “and the textile weighs about 2.6 pounds. The numbers are crazy.”

Researchers have long been intrigued by the unique properties of spider silk, which is stronger than steel or Kevlar but far more flexible, stretching up to 40 percent of its normal length without breaking. Unfortunately, spider silk is extremely hard to mass produce: Unlike silk worms, which are easy to raise in captivity, spiders have a habit of chomping off each other’s heads when housed together.

To get as much silk as they needed, Godley and Peers began hiring dozens of spider handlers to collect wild arachnids and carefully harness them to the silk-extraction machine. “We had to find people who were willing to work with spiders,” Godley said, “because they bite.”

By the end of the project, Godley and Peers extracted silk from more than 1 million female golden orb spiders, which are abundant throughout Madagascar and known for the rich golden color of their silk. Because the spiders only produce silk during the rainy season, workers collected all the spiders between October and June.

Then an additional 12 people used hand-powered machines to extract the silk and weave it into 96-filament thread. Once the spiders had been milked, they were released into back into the wild, where Godley said it takes them about a week to regenerate their silk. “We can go back and re-silk the same spiders,” he said. “It’s like the gift that never stops giving.”

Of course, spending four years to produce a single textile of spider silk isn’t very practical for scientists trying to study the properties of spider silk or companies that want to manufacture the fabric for use as a biomedical scaffold or an alternative to Kevlar armor. Several groups have tried inserting spider genes into bacteria (or even cows and goats) to produce silk, but so far, the attempts have been only moderately successful.
Part of the reason it’s so hard to generate spider silk in the lab is that it starts out as a liquid protein that’s produced by a special gland in the spider’s abdomen. Using their spinnerets, spiders apply a physical force to rearrange the protein’s molecular structure and turn it into solid silk.

“When we talk about a spider spinning silk, we’re talking about how the spider applies forces to produce a physical transformation from liquid to solid,” said spider silk expert Todd Blackledge of the University of Akron, who was not involved in creating the textile. “Scientists simply can’t replicate that as well as a spider does it. Every year we’re getting closer and closer to being able to mass-produce it, but we’re not there yet.”
For now, it seems we’ll have to be content with one incredibly beautiful cloth, graciously provided by more than a million spiders.

Images: 1) AMNH/R. Mickens 2) Nicholas Godley and Simon Peers
Hadley Leggett

Can Miracle Material Stop Radiation?

Gamma radiation is the most penetrating and energetic form of nuclear radiation.
To absorb half the incoming Gamma you need two and a half inches of concrete or almost half an inch of lead. So my eyebrows went up when I saw a press release for an organization called Radiation Shielding Technologies, or RST, selling protective clothing with this startling claim:

"DemronTM not only protects against particle ionizing/nuclear radiation (such as Beta and Alpha), but does what NO OTHER full body radiation protection can do: shield against X-ray and low-energy Gamma emissions."

This sounds like it merits either a Nobel Prize or an Ig Nobel, the award for bad science. Check their site and you’ll find details of an independent test claiming that their anti-radiation blanket really does stop a significant fraction of gamma (about 28 percent at a 90 degree angle).

What’s the secret? Well, the ‘blanket’ involved is 30 inches by 36 and weighs 60 pounds… So it’s basically equal to one-seventh of an inch of lead, and it works because it’s so dense. I checked with RST, and research scientist James Bradshaw agrees:

"You are correct in stating that in attenuation of gamma and x-ray radiation, cross-sectional density is the key parameter. A number of other much more minor effects are also at play, such as the role a supporting matrix has in excepting ejected electrons, etc. We do integrate heavy atomic absorbers into our material, though completely none toxic, that act as the primary attenuation component.
Our material meets or exceeds the absorption capabilities of lead by weight equivalent… Certainly, when it comes to high energy radiation, you can’t beat fundamental physics, but luckily you can get away from using lead."

The point of Demron is not that it has magical properties, but that it is more flexible and wearable than traditional lead-lined garments of the same weight; that blanket they tested might be easier to get over a radiation source than a lead one.
But in spite of RST’s fulsome press releases (including one which imaginatively likened the product to Iron Man’s armor), it’s not going to allow you to walk through heavily irradiated areas with impunity. As with many companies in the defense field, their science is fine but their marketing department may be prone to exaggeration.